机构地区:[1]Department of Physics,College of Science,China University of Mining and Technology [2]College of Medical Mechanism,Shanghai University of Science and Technology
出 处:《Chinese Physics B》2011年第1期631-638,共8页中国物理B(英文版)
基 金:Project supported by the Fundamental Research Funds for the Central Universities(Grant No.2010LKWL07);the National Basic Research Program of China(Grant No.2010CB226805)
摘 要:This paper reports that a series of Nd3+:Er3+:yb3+ co-doped borosilicate glasses have been prepared and their absorption spectra measured. The J-O intensity parameters Ωk (k = 2, 4, 6), spontaneous radiative lifetime Trad, spontaneous transition probability A, fluorescence branching ratio β and oscillator strength fed of the Nd3+ ions at room temperature are calculated based on Judd-Ofelt (J-O) theory. The temperature dependence of the up-conversion photoluminescence characteristics in a Nd3+:Er3+:Yb3+ co-doped sample is studied under a 978 nm semiconductor laser excitation, and the energy transfer mechanisms among Yb3+, Er3+ and Nd3+ ions are analysed. The results show that the J-O intensity parameters Ω2 increase when the Nd3+ concentration of the Nd3+:Er3+:yb3+ co-doped borosilicate glasses increases. The possibility of spontaneous transition is small and lifetimes are long at levels of 4F5/2 and 4F3/2. The intensity of Nd3+ emissions at 595, 691, 753, 813 and 887 nm axe markedly enhanced when the sample temperature exceeds 400 K. The reasons being the cooperation of the secondary sensitization from Era+ to Nd3+ and the contribution of a multi-phonon.This paper reports that a series of Nd3+:Er3+:yb3+ co-doped borosilicate glasses have been prepared and their absorption spectra measured. The J-O intensity parameters Ωk (k = 2, 4, 6), spontaneous radiative lifetime Trad, spontaneous transition probability A, fluorescence branching ratio β and oscillator strength fed of the Nd3+ ions at room temperature are calculated based on Judd-Ofelt (J-O) theory. The temperature dependence of the up-conversion photoluminescence characteristics in a Nd3+:Er3+:Yb3+ co-doped sample is studied under a 978 nm semiconductor laser excitation, and the energy transfer mechanisms among Yb3+, Er3+ and Nd3+ ions are analysed. The results show that the J-O intensity parameters Ω2 increase when the Nd3+ concentration of the Nd3+:Er3+:yb3+ co-doped borosilicate glasses increases. The possibility of spontaneous transition is small and lifetimes are long at levels of 4F5/2 and 4F3/2. The intensity of Nd3+ emissions at 595, 691, 753, 813 and 887 nm axe markedly enhanced when the sample temperature exceeds 400 K. The reasons being the cooperation of the secondary sensitization from Era+ to Nd3+ and the contribution of a multi-phonon.
关 键 词:Nd3+:Er3+:yb3+ co-doped borosilicate glasses optical parameters photoluminescence characteristics high temperature
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