硅烷化聚氨酯复合催化剂的研究  

STUDY ON A COMPOSITE CATALYST FOR SILYLATED POLYURETHANE

作　　者：段先健[1,2] 郑景新 康旭 丁明明[1] 郑丁[1] 谭鸿[1] 傅强[1] 

机构地区：[1]四川大学高分子科学与工程学院,成都610065 [2]广州吉必盛科技实业有限公司,广州510450

出　　处：《高分子学报》2011年第1期114-119,共6页Acta Polymerica Sinica

基　　金：教育部新世纪杰出人才计划(项目号NCET-08-0381);四川省杰出青年基金(基金号09ZQ026-024)资助项目

摘　　要：以聚丙二醇、TDI、N-正丁基-γ-氨丙基三甲氧基硅烷和蒙脱土为主要原料,采用原位聚合方法研究了蒙脱土和有机铋化合物对环境友好和储存稳定的硅烷化聚氨酯催化作用.通过滴定法测试了反应体系中异氰酸根(NCO)含量的变化,发现蒙脱土可以催化NCO与OH的反应,且与有机铋化合物具有协同效应,利用在线红外分析仪证实了蒙脱土的催化效应.使用FTIR对硅烷化聚氨酯预聚体进行了表征,并用加速老化法研究了复合催化剂对预聚体的储存稳定性的影响,结果表明硅烷化聚氨酯/蒙脱土复合材料具有良好的储存稳定性,具有开发应用前景.To obtain an environment friendly and stable silylated polyurethane /clay composite,a composite catalyst containing montmorillonite and organic bismuth compounds was developed for the preparation of polyurethane based on polypropylene glycol（PPG）,toluene diisocyanate（TDI）,N-butyl-γ-aminopropyl trimethoxysilane and montmorillonite via in situ polymerization.The montmorillonite can catalyze the reaction of isocyanate（NCO） and hydroxyl group（OH） effectively,and interestingly,a synergistic catalytic effect between montmorillonite and organic bismuth compound was observed in this system and verified by dibutylamine titration and online IR sptctrum measurement.Fourier transform infrared spectroscopy（FTIR） results showed that the silylated polyurethane prepolymer was successfully synthesized.In addition,the influence of the catalyst composition on the storage stability of prepolymer was evaluated with an accelerated aging method.The result indicated that all the silylated polyurethane/montmorillonite composite had relatively good storage stability.Furthermore,the montmorillonite-catalyzed silylated polyurethane prepolymers are found to be more stable than those catalyzed by organic bismuth compound,showing that the montmorillonite as a catalyst can not only catalyze the reaction between NCO and OH,but also inhibit the hydrolysis and condensation of the prepolymers,which was confirmed by using viscosity increases of these prepolymers induced with excessive miosture.Hence,our results provide a facile and effective composite catalyst for the preparation of silylated polyurethane,which holds great promise for further investigation and applications.

关 键 词：硅烷化聚氨酯 复合催化剂 蒙脱土 有机铋 

分 类 号：O643.36[理学—物理化学]