多金属氧簇催化研究进展  

Progress in Polyoxometalates Catalysis

作　　者：陈发旺[1] 胡长文[1] 

机构地区：[1]北京理工大学原子分子簇科学教育部重点实验室,北京100081

出　　处：《化学进展》2011年第1期19-41,共23页Progress in Chemistry

基　　金：国家自然科学基金项目(No.20731002);北京市教委(No.20091739006);高等学校学科创新引智计划(No.B07012)资助

摘　　要：多金属氧簇由于其组成和结构易于调控、具有酸性、氧化还原性、低毒性和低腐蚀性等优点,作为工业催化剂具有广阔的应用前景,是多酸化学领域的研究热点之一。本文综述了近5年来多金属氧簇在催化领域中研究的新进展,主要包括多金属氧簇的酸催化、氧化催化、双功能催化、加氢和活化二氧化碳合成碳酸酯等催化反应以及多金属氧簇的工业化应用等,并对未来发展趋势进行了展望。Polyoxometalates as industrial catalysts have been proven to have broad applications and prospects due to the advantages of their controllable composition and structures,strong acid and redox properties,low toxicity and corrosivity.Polyoxometalates catalysis is a hotspot in the field of polyoxometalates chemistry.The research situation and new progress in polyoxometalates catalysis in the last five years are reviewed,including acid catalysis,oxidation catalysis,bifunctional catalysis,other reactions containing hydrogenation and carbonate synthesis from carbon dioxide,and industrialization of polyoxometalate catalysis.In addition,the future development based on polyoxometalates catalysis is prospected.

关 键 词：多金属氧簇 酸催化 氧化催化 双功能催化 

分 类 号：O643.13[理学—物理化学] TQ426[理学—化学]