Ziegler-Natta催化剂催化1-丁烯聚合  

Polymerization of 1-butylene with Ziegler-Natta catalyst

作　　者：姜涛[1] 陈洪侠[1] 王伟众[2] 牛磊[1] 曹晨刚[1] 李健[1] 

机构地区：[1]天津科技大学材料科学与化学工程学院,天津300457 [2]中国石油天然气股份有限公司石油化工研究院大庆化工研究中心,黑龙江大庆163714

出　　处：《合成树脂及塑料》2011年第1期6-9,19,共5页China Synthetic Resin and Plastics

基　　金：教育部"高校新世纪优秀人才支持项目"(NCET-07-0142);黑龙江省高校"新世纪优秀人才培养计划"(NCET-06-010)资助

摘　　要：采用9,9-双(甲氧基甲基)芴(BMMF)作为内给电子体,制备了聚1-丁烯高效载体型Ziegler-Natta催化剂。研究了催化剂浓度、n(Al)/n(Ti)、聚合温度、外给电子体种类及用量对该催化剂催化1-丁烯聚合的影响,并将该催化剂与无内给电子体及以邻苯二甲酸酯(DNBP)为内给电子体的聚1-丁烯催化剂进行对比。结果表明:当催化剂浓度为0.05 mg/mL、n(Al)/n(Ti)为400、反应温度为20℃时,催化活性达2.856 kg/(g·h);当二异丁基二甲氧基硅烷与Ti的摩尔比为5时,聚合物等规指数达97.18%;以BMMF为内给电子体的催化剂的催化活性最高,以DNBP催化剂得到的聚1-丁烯等规指数最高。A high efficient supported Ziegler-Natta catalyst for polymerization of 1-butylene was prepared with 9,9-bis-（methoxymethyl）fluorene（BMMF） as internal electron donor. The effects of catalyst concentration, molar ratio of Al/Ti, polymerization temperature and type and content of external electron donor on polymerization of 1-butylene were studied. The catalyst so prepared was compared to catalyst without internal electron donor and catalyst with di-n-butyl phthalate（DNBP） as internal electron donor. The results show that the catalytic activity is up to 2.856 kg/（g·h） when catalyst concentration is 0.05 mg/mL, molar ratio of M/Ti is 400 and polymerization temperature is 20 ~C. The isotaeticity of poly（1-butylene） reaches 97.18% when the molar ratio of external electron donor diisobutyldimethoxysilane （DIBDMS）/Ti is 5. The catalyst with BMMF as internal electron donor has the highest activity and the poly（1-butene） prepared with the catalyst with DNBP as internal electron donor has the highest isotacticity.

关 键 词：聚1-丁烯 齐格勒-纳塔催化剂 9 9一双(甲氧基甲基)芴 内给电子体 

分 类 号：TQ325.14[化学工程—合成树脂塑料工业]