三苯氧基三对硝基苯氧基环三磷腈的合成与表征  

Synthesis and Characterization of Tri-phenoxy-tri-(4-nitrophenoxy)-cyclotriphosphazene

作　　者：丁炎可[1] 徐龙鹤[2] 

机构地区：[1]沈阳化工大学应用化学学院,辽宁沈阳110142 [2]沈阳化工研究院,辽宁沈阳110021

出　　处：《沈阳化工大学学报》2010年第4期303-307,共5页Journal of Shenyang University of Chemical Technology

摘　　要：以苯酚钠、对硝基苯酚钠和六氯环三磷腈(HCCTP)为原料合成三苯氧基三对硝基苯氧基环三磷腈,并采用FT-IR、1H-NMR、LC-MS、13C-NMR和31P-NMR对产物进行表征.以四氢呋喃为溶剂,采用摩尔比为1∶3∶3.5的HCCTP、苯酚钠和对硝基苯酚钠,反应温度65℃,反应时间7 h,得到三苯氧基三对硝基苯氧基环三磷腈.Tri-phenoxy-tri-（4-nitrophenoxy）-cyclotriphosphazene was synthesized by using sodium phenolate,sodium 4-nitrophenolate and hexachlorocyclotriphosphazene as raw materials.The product was characterized by FT-IR,1H-NMR,LC-MS,13C-NMR and 31P-NMR.HCCTP,sodium phenolate and sodium 4-nitrophenolate taken in the molar ratio of 1∶3∶3.5 were dissolved in tetrahydrofuran（THF）,reacting at 65 ℃ for 7 h and the product was gained.

关 键 词：六氯环三磷腈 三苯氧基三对硝基苯氧基环三磷腈 合成 

分 类 号：TQ126.2[化学工程—无机化工]