超声波降解全氟丁酸水溶液  

Degradation of perfluorobutyric acid in aqueous solution by ultrasound irradiation

作　　者：赵德明[1,3] 韩太平[1] Hoffmann Michael R. 徐新华[3] 

机构地区：[1]浙江工业大学化学工程与材料学院,浙江杭州310032 [2]W.M.Keck Laboratories,California Institute of Technology,California Pasadena 91125,USA [3]浙江大学环境与资源学院,浙江杭州310027

出　　处：《化工学报》2011年第2期502-506,共5页CIESC Journal

基　　金：中国博士后科学基金项目(20100471716);浙江省自然科学基金项目(Y5100075)~~

摘　　要：引言全氟丁酸（PFBA）作为全氟辛烷磺酸基化合物（PFOS）和全氟辛酸化合物（PFOA）的替代品,相对于PFOS和PFOA,因水溶解度更大和碳链短等特点造成PFBA更难处理和代谢[1-2]。The feasibility of perfluorobutyric acid（PFBA）degradation by ultrasound irradiation was investigated and the influential factors such as ultrasonic frequency,initial PFBA concentration,sorts of saturated gas and reaction temperature were also evaluated.The experimental results showed that PFBA degradation followed the apparent pseudo-first order kinetic reaction.The sonolysis was completed over a range of frequency from 20 kHz to 1060 kHz at the initial PFBA concentration of 0.47×10-6 mol·L-1.However,the PFBA degradation rate constants had an apparent maximum at 610 kHz.Under the 610 kHz ultrasound irradiation,the initial PFBA concentration and the sorts of saturated gas affected greatly the PFBA degradation,and the reaction temperature had a slight effect on the PFBA degradation.In addition,the PFBA degradation in the manufacture wastewater was also evaluated under 610 kHz ultrasound.

关 键 词：全氟丁酸 超声波 动力学 降解 

分 类 号：X78[环境科学与工程—环境工程] TQ209[化学工程—有机化工]