基于含氮羧酸配体碱土金属配合物的研究进展  

Study and Progress in Alkaline Earth Metal Compound B Ased on N-containing Carboxylate Ligand

作　　者：陈友存[1] 许军军[1] 

机构地区：[1]安庆师范学院化学化工学院功能配合物安徽省重点实验室,安徽安庆246011

出　　处：《安庆师范学院学报（自然科学版）》2010年第4期69-73,共5页Journal of Anqing Teachers College(Natural Science Edition)

基　　金：国家自然科学基金(No.20771006)资助

摘　　要：基于配位作用以及配体之间的多种弱相互作用(如氢键、π-π堆垛作用等),金属离子与有机配体之间经自组装形成结构新颖、性能独特的金属—有机超分子配合物,本文主要介绍了配位化学和金属—有机超分子框架结构的基本原理及其研究方法。In recent years,based on coordinative interactions and diversified supramolecular interactions（such as hydrogen bonding and π-π stacking,etc.）,the formation of metal-organic supermolecular compounds with novel structures and properties by self-assembling between metal ions and organic ligand have been the most intensive research topic in crystal engineering of metal complexes,coordination chemistry and supermolecular chemistry.The research of metal-organic supramolecular frameworks is one of the hot topic in supramolecular interactions.Here,the concepts and principles of coordination chemistry,supramolecular chemistry and metal-organic frameworks（MOFs） are simply introduced.

关 键 词：有机金属化合物 π-π堆垛作用 自组装 

分 类 号：O65[理学—分析化学]