吡啶酰胺基配体与Mn^(2+)、Fe^(3+)、Ru^(3+)配合物的合成和催化环己烯的氧化反应  

SYNTHESIS OF COMPLEXES OF LIGANDS CONTAINING PYRIDINECARBOXAMIDE WITH Mn^(2+)、Fe^(3+)、Ru^(3+) AND CATALYTIC OXIDATION OF CYCLOHEXENE

作　　者：戚建英[1] 杨启云[2] 胡家元[1] 韩银仙 邓立生 李贤均[1] 

机构地区：[1]四川大学化学学院有机金属络合催化研究所,成都610064 [2]云南师范大学化学系,昆明650031

出　　处：《化学研究与应用》1999年第5期535-536,共2页Chemical Research and Application

摘　　要：The Complex of the ligands containing pyridinecarboxamide with Mn2+, Fe3=,Ru3+ had been Synthesized. The composition andstructure of the metal complex had been determined by UV, IR.TG, XPS and elemental analysis .When the oxidation of cyclohexenewas catalyzed by the complexes with oxygen as oxided, the conversion reached 45.7%, the seleCtivity of cyclohexenone is 64.6%.Ruthenium complexes exhibits better selectivity for 1,2-cyclohexene oxide.The Complex of the ligands containing pyridinecarboxamide with Mn2+, Fe3=,Ru3+ had been Synthesized. The composition andstructure of the metal complex had been determined by UV, IR.TG, XPS and elemental analysis .When the oxidation of cyclohexenewas catalyzed by the complexes with oxygen as oxided, the conversion reached 45.7%, the seleCtivity of cyclohexenone is 64.6%.Ruthenium complexes exhibits better selectivity for 1,2-cyclohexene oxide.

关 键 词：吡啶甲酰胺 配合物 环己烯 氧化 催化剂 锰 铁 

分 类 号：O643.36[理学—物理化学] O624.12[理学—化学]