[Co(p-Me-PPA)_2,(H_2O)_2]Cl的合成及其催化环己烯氧化反应的研究  

STUDY ON SYNTHESIS OF COMPLEX [Co(p-Me-PPA)_2(H_2O)_2]Cl AND CATALYTIC OXIDATION OF CYCLOHEXENE

作　　者：戚建英[1] 马红霞[1] 杨启云[2] 胡家元[1] 李贤均[1] 

机构地区：[1]四川大学化学学院有机金属络合催化研究所,成都610064 [2]云南师范大学化学系,昆明650031

出　　处：《化学研究与应用》1999年第5期537-538,共2页Chemical Research and Application

摘　　要：Complex Cobalt(III) di[N-(p-methyl)phenyl-2 -pyridinecarboxamide] dihydrate chloride [Co(p-Me-PPA)2(H2O)2] Cl hadbeen synthesised. The single crystal strUcture of the metal complex had been successfully prepared and determined by fourcircle single crystal diffractometer. When the oxidation of cyclohexene was catalyzed by [Co(p-Me-PPA)2(H2O)2]Cl withmolecular oxygen as oxidant, the conversion reached 59% , the selectivity of cyclohexenone being 75%.Complex Cobalt(III) di[N-(p-methyl)phenyl-2 -pyridinecarboxamide] dihydrate chloride [Co(p-Me-PPA)2(H2O)2] Cl hadbeen synthesised. The single crystal strUcture of the metal complex had been successfully prepared and determined by fourcircle single crystal diffractometer. When the oxidation of cyclohexene was catalyzed by [Co(p-Me-PPA)2(H2O)2]Cl withmolecular oxygen as oxidant, the conversion reached 59% , the selectivity of cyclohexenone being 75%.

关 键 词：吡啶甲酰胺 钴配合物 环己烯 氧化 催化剂 

分 类 号：O643.36[理学—物理化学] O624.12[理学—化学]