铁 锡多核金属有机化合物的合成及表征  

Synthesis and Characterization of Multi nuclear Organotin iron Compounds

作　　者：路军 白银娟[1] 靳建辉 杨秉勤[1] 马怀让[1] 

机构地区：[1]西北大学化学系,西安710069

出　　处：《应用化学》1999年第5期82-84,共3页Chinese Journal of Applied Chemistry

基　　金：陕西省自然科学基金

摘　　要：Five title complexes: Fc CO 2SnPh 3, (FcCO 2) 2SnBu 2, ｛[(FcCO 2)SnBu 2] 2O｝ 2, FcC(CH 3) CHCO 2SnPh 3 , ｛[(FcC(CH 3) CHCO 2) SnBu 2] 2O｝ 2 , (Fc=( η 5 C 5H 5)Fe( η 5 C 5H 4—)) have been synthesized via reactions of ferrocenecarboxylic acid or 3 ferrocenyl 2 crotonic acid with triphenyltin hydroxide or di n butyltin oxide. All of the compounds have been characterized by elemental analysis, IR, 1H NMR and MS.Five title complexes: Fc CO 2SnPh 3, (FcCO 2) 2SnBu 2, ｛[(FcCO 2)SnBu 2] 2O｝ 2, FcC(CH 3) CHCO 2SnPh 3 , ｛[(FcC(CH 3) CHCO 2) SnBu 2] 2O｝ 2 , (Fc=( η 5 C 5H 5)Fe( η 5 C 5H 4—)) have been synthesized via reactions of ferrocenecarboxylic acid or 3 ferrocenyl 2 crotonic acid with triphenyltin hydroxide or di n butyltin oxide. All of the compounds have been characterized by elemental analysis, IR, 1H NMR and MS.

关 键 词：有机锡羧酸酯 铁 锡 多核 二茂铁羧酸 合成 

分 类 号：O627.42[理学—有机化学]