六氟磷酸二(4,4’-二甲基-2,2’-联吡啶)(2,2’-联吡啶-4,4’-二羧酸)合钌(Ⅱ)的二维核磁共振  

Two Dimensional Nuclear Magnetic Resonance Analysis of Ruthenium- (4,4' -dimethyl-2,2'-bipyridine) _2 (2,2'-bipyridine-4,4'-dicarboxylic Acid) (PF_6)_2

作　　者：王鹏[1] 袁艺[1] 景晓燕[2] 朱果逸[1] 

机构地区：[1]中国科学院长春应用化学研究所国家电化学和光谱研究分析中心,长春130022 [2]哈尔滨工程大学化学工程系,哈尔滨150001

出　　处：《分析化学》1999年第11期1337-1340,共4页Chinese Journal of Analytical Chemistry

基　　金：国家'九五'攻关重点资助项目(批准号96-A23-03-01)

摘　　要：用~1H NMR和^(13)C NMR谱研究了新型电化学发光探针六氟磷酸二(4,4’-二甲基-2,2’-联吡啶)·(4,4’-二羧酸-2,2’-联吡啶)合钌(Ⅱ)的立体结构,通过~1H^(-1)H COSY、^(13)C^(-1)H HETCOR谱对其氢谱和碳谱中的各谱峰进行了归属,并给出了氢谱和碳谱峰的化学位移值.The 1H and 13C NMR spectra are reported for Ru(4,4'-dimethyl-2, 2'-bipyridine)2 (2,2'-bipyridine-4,4'-dicarboxylic acid) (PF6)2 that can be used as a new electrochemiluminescent probe in immunoasssay and nucleic acid hybridization assay. Because of the effect of Ru atom on ligands and complex steric configuration, it is difficult to attribute spectra of the title molecular. By using 2D 1 H-1H COSY and 1 H-13C HETCOR method, the proton and 13C NMR spectra are assigned completely, which provides a satisfactory method to quantitative and qualitative analysis of the title moleculer in the further study.

关 键 词：钌 配合物 联吡啶 电化学发光 探针 NMR 

分 类 号：O614.821[理学—无机化学]