新型八取代基酞菁锌的合成与表征  

Synthesis and Characterization of New Octa-substituents Phthalocyanine Zinc

作　　者：朱运德[1] 韩双[1] 姚纪欢[1] 夏道成[1,2] 任鸿飞[1] 杨世承[1] 郭艳杰[1] 郑新星[1] 刘春暘[1] 

机构地区：[1]运城学院应用化学系,山西运城044000 [2]东北师范大学化学学院,吉林长春130012

出　　处：《山西大同大学学报（自然科学版）》2010年第6期38-40,88,共4页Journal of Shanxi Datong University(Natural Science Edition)

基　　金：国家自然科学基金资助项目[61006034];山西省青年基金项目[2010021010-3];运城学院院级重点项目[975175];东北师范大学校内博士后项目[111900026]

摘　　要：首次使用苯二甲腈和硫酸锌反应合成新型的八取代基酞菁锌.合成方法:苯二甲腈和硫酸锌在DMF中搅拌恒温加热,并加入适量的催化剂1,8-二氮杂-双环(5,4,O)十一碳烯-7(DBU),反应完毕后,得到目标化合物.通过对产物进行红外、紫外可见光谱、荧光和X-RD的测试,表征其结构,从而证实产物就是目标化合物.In this article,we first take phthalonitrile and ZnSO4 as the starting reactants to prepare octa-substituted phthalocyanine zinc.The mixture of phthalonitrile and ZnSO4were used as precursors to synthesis octa-substituted phthalocyanine zinc which was generated by cyclotetramerisation in the presence of 1,8-diazabicyclo undec-7-ene（DBU）.At last,the compound was characterized by infrared,fluorescence and UV-visible spectrum and atomic absorption,proving its structure.Thus it confirmed that the product was the target compound.

关 键 词：酞菁 酞菁锌 合成 表征 

分 类 号：O631.1[理学—高分子化学]