Determination of 2 Amides Pesticide Residues in Agricultural Products by Terahertz Time-domain Spectroscopy  被引量:14

太赫兹时域光谱检测农产品中2种酰胺类农药残留研究(摘要)(英文)

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作  者:王孝伟[1] 王强[1] 王花丽[1] 

机构地区:[1]中国计量学院质量与安全工程学院,浙江杭州310018

出  处:《Agricultural Science & Technology》2010年第8期53-56,共4页农业科学与技术(英文版)

基  金:Supported by Special Fund for Scientific Research on Public Welfare by China Quality Monitoring Bureau (200910181);National Natural Science Foundation of China (60902095)~~

摘  要:[Objective] The aim was to explore the application of terahertz (THz) technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides (butachlor and metolachlor) were measured by THz time-domain spectroscopy (THz-TDS) under conditions of room temperature and nitrogen,meanwhile their refractive index and absorption coefficient between 0.2 and 2.2 THz were calculated by using models based on Fresenl equations. [Result] The 2 pesticides both had a series of different characteristic absorption peaks between 0.2 and 2.2 THz,respectively. Their molecular structures were similar,but there were great difference in absorption and refractive index spectrum between them. [Conclusion] THz-TDS technique is feasible to detect pesticide residues,especially there is a greater advantage in identifying the structure of similar substances.[目的]探讨THz技术在农药识别和残留量检测中的应用。[方法]利用太赫兹时域光谱(THz-TDS)技术对2种除草剂丁草胺和异丙甲草胺在室温氮气环境下的THz远红外光谱特性进行测定,并利用菲涅尔公式的数据处理模型得到其在0.2~2.2THz波段的折射率和吸收系数。[结果]2种农药在0.2~2.2THz波段内分别存在不同的特征吸收峰。尽管2种农药分子结构相似,但其吸收谱和折射率却存在很大差异。[结论]THz-TDS技术在农药微量残留检测方面是可行的,特别是在识别结构较为相似的物质上有较大优势。

关 键 词:Terahertz wave Pesticide residue THZ-TDS BUTACHLOR METOLACHLOR 

分 类 号:S481.8[农业科学—农药学]

 

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