PPESK-PPS共混合金的研究  

Study on PPESK PPS blends

作　　者：张军[1] 蹇锡高[1] 朱秀玲[1] 刘彦军[1] 彭静[1] 王瑞玲[1] 

机构地区：[1]大连理工大学高分子材料系

出　　处：《大连理工大学学报》1999年第3期405-409,共5页Journal of Dalian University of Technology

基　　金：国家"九五"重点科技攻关项目

摘　　要：以溶液共混—共沉淀的方式制备了含二氮杂萘联苯结构的聚醚砜酮－聚苯硫醚共混物；用熔融指数仪研究了共混物的加工性能，用ＤＳＣ考察了共混物的热性能，用ＰＬＭ、ＷＡＸＤ研究了共混物的结晶行为，用ＩＲ分析了两组分的相容性．结果表明：ＰＰＳ可显著改善ＰＰＥＳＫ的加工性能；在一定范围内，ＰＰＥＳＫ不影响ＰＰＳ的晶型，但降低了ＰＰＳ的结晶度；Polymer blends of poly(phthalazinone ether sulfone ketone) (PPESK) and poly(phenylene sulfide) (PPS) were prepared by coprecipation from solution of blends. The processability, thermal properties, crystallization and compatibility of blends were studied by means of melt flow indexer ( MFI ), differential scanning caloremeter(DSC), wide angle X ray scattering(WAXD) and infred spectra(IR). The results show that the processibility of PPESK can be greatly improved by adding a small amount of PPS;in certain range, the presence of PPESK does not affect the type of crystalline of PPS but decreases the crystallinity of PPS;the IR result confirms that the system of PPESK PPS is imcompatible.

关 键 词：聚苯硫醚 热塑性塑料 PPESK 聚醚砜酮 共混物 

分 类 号：TQ326.5[化学工程—合成树脂塑料工业]