单电子转移活性自由基聚合的现状及展望  

Current Situation and Perspectives of Single Electron Transfer Living Radical Polymerization

作　　者：丁伟[1] 孙颖[1] 吕崇福[1] 魏继军[1] 于涛[1] 

机构地区：[1]东北石油大学化学化工学院,大庆163318

出　　处：《应用化学》2011年第3期245-253,共9页Chinese Journal of Applied Chemistry

基　　金：黑龙江省自然科学基金重点项目(ZJG0507);黑龙江省自然科学基金青年基金(QC08C33);黑龙江省研究生创新科研资金(YJSCX2008-044HLJ);黑龙江省科技厅攻关项目(GZ05A404)资助

摘　　要：重点介绍了单电子转移活性自由基聚合的机理及适合该聚合体系的催化剂、配体、溶剂种类和单体适用范围,并探讨了单电子转移活性自由基聚合的发展前景。In this paper, we mainly discussed the involved mechanism in single electron transfer living radical polymerization. The types of catalysts, ligands, solvents as well as monomers suitable for such kinds of polymerizations have been also addressed in detail. In addition, the perspectives of this single electron transfer living radical polymerization was highlighted.

关 键 词：活性聚合 单电子转移活性自由基聚合 机理 外层电子转移 异裂 

分 类 号：O631.5[理学—高分子化学]