某制药企业生产废水难降解负荷的溯源研究  

Trace to the source of refractory organic loading in processing wastewater of a pharmaceutical enterprise

作　　者：熊贞晟[1,2] 刘锐[2] 穆春芳 李荧 蔡强 张永明[1] 陈吕军[2,3] 

机构地区：[1]上海师范大学生命与环境科学学院,上海200234 [2]浙江清华长三角研究院生态环境研究所,浙江嘉兴314006 [3]清华大学环境科学与工程系,北京100084

出　　处：《环境污染与防治》2011年第1期1-4,7,共5页Environmental Pollution & Control

基　　金：国家“十一五”科技支撑计划项目(No.2006BAC02A16);嘉兴市科技计划项目(No.2007AY1016)

摘　　要：研究了某制药企业各车间生产废水的可生化性,评价了各车间废水对废水总量、COD排放量、难降解COD(CODNB)的贡献率,筛查了CODNB的主要来源。结果表明,香叶酯、虾青素、植酸酶、酮苷的单位产品(以每吨计,下同)废水产生量分别为125、420、27、266 t,单位产品COD排放量分别为1.5、13.3、0.6、11.3 t。香叶酯-4车间排出的废水可生化性最差,香叶酯-4、香叶酯-2和虾青素-3等车间的废水是该企业污水站处理出水中CODNB的主要来源,也是影响污水站出水水质的主要因素。Biodegradability of wastewater from different processing workshops in a pharmaceutical enterprise was studied,based on which the devotion of each processing workshops to the discharged volume,COD and non-biodegradable COD（CODNB） was evaluated and the main contributors of CODNB were screened.Study showed that 125,420,27 and 266 t of wastewater was discharged respectively for production of per unit of geranyl,astaxanthin,phytase and ketoside,and the corresponding discharged COD was 1.5,13.3,0.6 and 11.3 t.Wastewater from the processing workshop of geranyl-4 was of the most refractory,while wastewater from the processing workshop of astaxanthin-4 was the most biodegradable one.CODNB in the effluent of the wastewater treatment plant was primarily attributed to wastewater from processing workshops of geranyl-2,geranyl-4,astaxanthin-4 and ketoside,which limited further improvement of the effluent quality.

关 键 词：制药废水 生物处理 可生化性 

分 类 号：X703[环境科学与工程—环境工程]