Cu-Ni/γ-Al_2O_3双功能催化剂上二甲醚水蒸气重整制氢:焙烧温度的影响  

Steam reforming of dimethyl ether over Cu–Ni/γ-Al_2O_3 bi-functional catalyst:Effect of calcination temperature

作　　者：邹卫兵[1,2] 潘相敏[2,3] 王晓蕾[2,4] 寇素原[2,3] 马建新[2,3] 

机构地区：[1]华东理工大学资源与环境工程学院,上海200237 [2]同济大学新能源汽车工程中心,上海201804 [3]同济大学汽车学院,上海201804 [4]同济大学环境科学与工程学院,上海200092

出　　处：《化工进展》2011年第3期547-551,共5页Chemical Industry and Engineering Progress

基　　金：同济大学-壳牌公司国际合作项目(20071193)

摘　　要：采用沉积-沉淀法制备了一系列不同焙烧温度的二甲醚水蒸气重整制氢催化剂2Cu-1Ni/5γ-Al2O3(摩尔比),考察了焙烧温度对催化剂2Cu-1Ni/5γ-Al2O3的结构及催化性能的影响,并运用N2吸附-脱附(BET)、H2程序升温还原(H2-TPR)、X射线衍射(XRD)等手段对催化剂进行了表征与分析。结果表明,500℃焙烧的催化剂BET比表面积及孔容、孔径适中。随着焙烧温度的升高,以尖晶石态存在的铜组分比例逐渐增加,金属Cu的粒径也从12.6 nm增至33.2 nm。适当的焙烧温度可保证金属和载体之间的强度适中的作用力,从而保证催化剂具有较优的活性和稳定性。催化剂活性随着焙烧温度的增加先升高后减小,较优的焙烧温度为500℃。2Cu-1Ni/5？-Al2O3 catalysts were prepared by the deposition precipitation method for dimethyl ether steam reforming（DME SR）reaction.The effect of the different calcination temperature on catalyst structure and performance was investigated by using Brunauer-Emmett-Teller（BET）method,H2 temperature-programmed reduction（H2-TPR）,and X-ray diffraction（XRD）.The results showed that the effect of calcination temperature on the catalyst was remarkable.The catalyst calcined at 500 ℃ had moderate BET surface area,pore volume and average pore diameter.As calcination temperature rose,the content of spinel copper increased,and the particle diameter of metal copper also increased.An appropriate calcination temperature could ensure a suitable strength of interaction between metal and carrier to achieve higher reactivity and stability.The optimum calcination temperature was 500 ℃.

关 键 词：Cu-Ni基催化剂 焙烧温度 水蒸气重整 二甲醚 沉积-沉淀法 

分 类 号：O643.3[理学—物理化学]