Meso-四(3-甲基吡啶基)锰卟啉的合成及其放氧性能  

THE SYNTHESIS OF MESO-TETRA (3-METHYIPYRLDYL) MANGNESE PORPHYRIN COMPLEX AND PROPERTY OF EVOLUTION OXYGEN

作　　者：王秀华[1] 高福[1] 

机构地区：[1]中国科学院兰川化学物理矿究所

出　　处：《太阳能学报》1990年第1期27-31,共5页Acta Energiae Solaris Sinica

摘　　要：本文报道了Meso-四(3-甲基吡啶基)锰卟啉的合成,并以它为光敏剂,氧化钌为催化剂,苯醌为电子受体,采用正交法进行了可见光放氧性能试验。试验表明,体系有较高放氧活性,提出了可能的四电子放氧机理。This paper presents the result of synthesis of meso-tetra (3-methyl pyridyl) mangnese complex as well as the experiment on visible light induced oxgen evolution in which the complex was used as a sensitizer, RuO2 served as the catalyst and quinone acted the electron acceptor. In order to optimize the reaction conditions, the orthogonal method was used in the experiment. The results indicated that the complex system performed a higher activity for oxygen evolution from water. A possible mechanism of oxygen producing through four electron transfer was proposed.

关 键 词：四锰卟啉 MESO 放氧甲基吡啶基 

分 类 号：TQ137.12[化学工程—无机化工]