有机-无机盐(C_4H_(12)O_3N)_3PW_(12)O_(40)·11H_2O的合成、表征和对亚硝酸根的电催化还原  

Synthesis, characterization of organic-inorganic salt (C 4H 12 O 3N) 3PW 12 O 40 ·11H 2O and its electrocatalytic reduction for nitrite

作　　者：毕丽华[1] 刘景华[1] 王恩波[1] 黄如丹[1] 郭树荣[1] 

机构地区：[1]东北师范大学化学学院,吉林长春130024

出　　处：《东北师大学报（自然科学版）》1999年第3期102-105,共4页Journal of Northeast Normal University(Natural Science Edition)

基　　金：国家自然科学基金

摘　　要：合成了未见文献报道的有机－ 无机盐（Ｃ４Ｈ１２ Ｏ３Ｎ）３ＰＷ１２ Ｏ４０·１１Ｈ２Ｏ利用元素分析、红外光谱、电子光谱和热重差热等测试手段，对其结构进行了表征，并初步探讨了它的电化学性质及对ＮＯ２ －The unprecedented organic-inorganic salt (C 4H 12 O 3N) 3PW 12 O 40 ·11H 2O was synthesized and characterized by elemental analysis, IR spectrum, UV spectrum and TG-DTA spectrum. Its electrochemical properties in aqueous solution were studied and the results showed that title complex exhibits good catalysis for the reduction of NO 2 -.

关 键 词：钨磷杂多化合物 有机-无机盐 电催化作用 

分 类 号：O614.613[理学—无机化学]