UV/Fenton试剂处理高浓度含酚废水的实验研究  

Experimental Study on Treatment of Wastewater Containing Highly Concentrated Phenol with UV/Fenton Reagent

作　　者：张大松[1] 高洪阁[1] 商洁[1] 王涛[1] 

机构地区：[1]山东科技大学化学与环境工程学院,山东青岛266510

出　　处：《山东科技大学学报（自然科学版）》2011年第1期92-95,共4页Journal of Shandong University of Science and Technology(Natural Science)

摘　　要：研究UV/Fenton试剂中各个因素对降解高浓度含酚废水的影响,确定UV/Fenton法处理高浓度含酚废水的最佳工艺条件。保持UV/Fenton体系的基准条件不变,通过改变pH值、H2O2浓度、Fe2+浓度、反应时间等实验条件,考察这些因素对UV/Fenton法处理高浓度含酚废水效果的影响。结果表明,UV/Fenton试剂对高浓度含酚废水有较好的去除效果和较高的反应速率。当苯酚初始浓度为1 000mg/L时,紫外光波长为253.7nm,反应时间为25～40min,pH值为6～7,H2O2浓度为40～50mmol/L,Fe2+浓度为28～30mg/L时,苯酚去除率可达90%以上,满足后续生物降解要求。The paper studied the impact of various factors of UV/Fenton reagent on the degradation of wastewater containing highly concentrated phenol and determined the best technological conditions of water treatment.Keeping the basic reaction conditions of the UV/Fenton system constant,we investigated the influence of these factors on the effect of the treatment of wastewater containing highly concentrated phenol by changing the experimental conditions such as pH value,concentration of H2O2,concentration of Fe2＋and reaction time,etc.The experiment results show that the UV/Fenton reagent has a better removal effect and a higher reaction rate than the traditional methods.The removal rate of phenol is over 90% with the following conditions： initial phenol concentration of wastewater is 1 000 mg/L,UV wavelength is 253.7 nm,reaction time is 25-40 min,pH value is 6-7,the concentration of H2O2 and Fe2＋ are 40-50 mmol/L and 28-30 mg/L respectively,satisfying the requirements of follow-up biodegradation.

关 键 词：UV/Fenton试剂 高级氧化技术 含酚废水 苯酚去除率 化学需氧量 

分 类 号：TB499[一般工业技术]