咔咯锰、铁和钴配合物的合成与应用研究进展  

Research progress on the synthesis and applications of manganese,iron and cobalt corrole complexes

作　　者：林文生[1] 朱卫华[1] 路桂芬[1] 欧忠平[1] 

机构地区：[1]江苏大学化学化工学院,江苏镇江212013

出　　处：《应用化工》2011年第2期319-323,共5页Applied Chemical Industry

基　　金：国家自然科学基金资助项目(21071067);江苏省自然科学基金资助项目(BK2008226)

摘　　要：金属咔咯是具有独特的光化学、光物理、光生物性质的多功能卟啉类配合物。特别是一些含有过渡金属如锰、铁、钴为中心离子的金属咔咯配合物,在新型催化剂、抗肿瘤药物、电化学传感器以及纳米材料等领域都具有较好的应用前景。对含有锰、铁、钴中心金属离子的单核和双核咔咯配合物的合成方法及在相关领域的应用进展进行了综述,为该类配合物的进一步研究和应用提供有益参考。Metallocorroles are porphyrin-like complexes with unique photochemical,photophysical and photobiological properties.Particularly,the metallocorroles containing a transition metal such as manganese,iron or cobalt as the central ions of the complexes have good potential applications in the field of novel catalysts,anti-cancer drugs,electrochemical sensors and nano-materials.The research progress on synthesis methods of the mono-and bis-nuclear corroles containing manganese,iron or cobalt ions as well as on their applications in some related fields were summarized and reviewed,and which might provide a useful reference for the further research and application of these complexes.

关 键 词：锰、铁、钴咔咯配合物 合成 应用 

分 类 号：O626.13[理学—有机化学]