新型超分子化合物C_6H_(20)N_2O_(64)P_2Mo_(18)·8H_2O的晶体结构及电催化作用  

Thc Crystal Structure and Electrocatalysis of Supermolecular Compound C_6H_(20)N_2O_(64)P_2Mo_(18)·8H_2O

作　　者：刘景华[1] 辛明红[1] 王恩波[1] 彭军[1] 毕丽华[1] 

机构地区：[1]东北师范大学化学系,长春130024

出　　处：《高等学校化学学报》1999年第9期1343-1345,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金!29771006

摘　　要：A novel compound formulated [NH2(CH2)4CHNH2COOH]H6P2Mo18O62 has been synthesized and its structure has been characterized, which is the first example of aminoacid-heteropolyacid species. Crystal system is orthorhombic, space group P21212, unit cell dimensions: α=1. 572 2(3) nm, b=2.118 1 (4) nm, c=1.238 3(3) nm, α=90.04(3)°, β=90.00 (2)°, γ= 89. 99 (3)°, V = 4.123 6(14) nm3, Z=2, D0=2.437×103 kg/m3, R=0.038 7. Experimental result shows that the title compound has electrocatalysis reactivity.A novel compound formulated [NH2(CH2)4CHNH2COOH]H6P2Mo18O62 has been synthesized and its structure has been characterized, which is the first example of aminoacid-heteropolyacid species. Crystal system is orthorhombic, space group P21212, unit cell dimensions: α=1. 572 2(3) nm, b=2.118 1 (4) nm, c=1.238 3(3) nm, α=90.04(3)°, β=90.00 (2)°, γ= 89. 99 (3)°, V = 4.123 6(14) nm3, Z=2, D0=2.437×103 kg/m3, R=0.038 7. Experimental result shows that the title compound has electrocatalysis reactivity.

关 键 词：超分子化合物 电催化剂 赖氨酸盐 钼磷酸 

分 类 号：O643.36[理学—物理化学] O614.612[理学—化学]