5-(4-烟酸酰亚胺基)苯基-10,15,20-三苯基卟啉及其锌配合物的合成及性质研究  

Preparation and Properties of 5-(4-Nicotinicaminophenyl)-10,15,20-triphenylporphyrin and Its Zn Complexes

作　　者：庄长福[1,2] 孙园园[1] 王运方[1] 石建慧[1] 师宇华[1] 师同顺[1] 

机构地区：[1]吉林大学化学学院,长春130023 [2]西南林业大学木质科学与装饰工程学院,昆明650224

出　　处：《化学学报》2010年第22期2319-2324,共6页Acta Chimica Sinica

基　　金：国家自然科学基金(No.20801022)资助项目

摘　　要：合成了未见文献报道的5-(4-烟酸酰亚胺基)苯基-10,15,20-三苯基卟啉配体(H2P)及其锌配合物(ZnP),并通过紫外-可见光谱、红外光谱、核磁共振氢谱、元素分析等测试方法对化合物的结构加以确认,研究了配体和配合物的荧光光谱的变化和电化学性质.热分析研究表明,卟啉配体及配合物显示了很高的热稳定性,超过390℃才开始分解.The new 5-（4-nicotinicaminophenyl）-10,15,20-triphenylporphyrin ligand（H2P） and its complexe ZnP have been synthesized and confirmed by means of elemental analyses,UV-Vis spectra,FT-IR spectra and 1H NMR spectra.Fluorescence spectra of the porphyrin ligand and the complexes were investigated.We also studied the electrochemistry of the ligand and the complexes.The results showed that there are much difference between the ligand and the complexes of the UV-Vis spectra,infrared spectra,and fluorescence spectra.The cyclic voltammetry of the ligand and ZnP are investigated.The thermal studies show that the porphyrins have higher thermal stability and could be decomposed until 390 ℃.

关 键 词：卟啉 配合物 合成 荧光光谱 电化学 

分 类 号：O627.4[理学—有机化学]