Mukaiyama缩合的取代基效应(英文)  

Substituent Effect in Mukaiyama Condensation

作　　者：王强[1] 张滂[1] 

机构地区：[1]北京大学化学系

出　　处：《合成化学》1999年第2期159-163,169,共6页Chinese Journal of Synthetic Chemistry

摘　　要：合成了４－三甲硅氧基－，４－苄氧基－，４－甲氧基－和４－氯苯乙酮的烯醇三甲硅醚，并使之与相应的酮以及４－氯－和４－硝基苯乙酮发生Ｍｕｋａｉｙａｍａ缩合反应。The trimethylsilyl enol ethers of 4trimethylsilyloxy,4benzyloxy,4methoxy,and 4chloroacetophenone were prepared and caused to condense with their respective ketones as well as 4chloro, 3 and 4nitroacetophenone by Mukaiyama method and the yields of aldols were discussed in view of their substituent effects.

关 键 词：羟苯乙酮 羟醛 Mukaiyama缩合 取代基效应 合成 

分 类 号：O623.549[理学—有机化学]