邻菲罗啉-氨基酸铜(Ⅱ)配合物的合成及表征  

Synthesis and Characterization of Copper() Complexeswith 1,10Phenanthroline and Amino Acid

作　　者：周晓华[1] 李明华[1] 乐学义[1] 

机构地区：[1]华南农业大学理学院应用化学系

出　　处：《合成化学》1999年第2期213-215,共3页Chinese Journal of Synthetic Chemistry

摘　　要：合成了三种邻菲罗啉（Ｐｈｅｎ）－氨基酸酮（Ⅱ）的配合物：［Ｃｕ（Ｐｈｅｎ）（Ｌ－Ｈｉｓ）］·２ＣｌＯ４·Ｈ２Ｏ，［Ｃｕ（Ｐｈｅｎ）（Ｇｌｙ）］·ＣｌＯ４·Ｈ２Ｏ和［Ｃｕ（Ｐｈｅｎ）（Ｌ－Ｐｒｏ）］·ＣｌＯ４·０．５Ｃ２Ｈ５ＯＨ（Ｌ－Ｈｉｓ：组氨酸；Ｇｌｙ：甘氨酸：Ｌ－Ｐｒｏ：脯氨酸）。用元素分析、摩尔电导。Three new complexes of copper() with 1,10phenanthroline and amino acid (LHistidine,Glycine, LProline) have been synthesized and characterized by elemental analysis, molar conductance, infrared spectra, eletronic absorption spectra. The compositions of the complexes are confirmed separately to be 2ClO4H2O, ClO4H2O and ClO40.5C2H5OH.

关 键 词：邻菲罗啉 铜 配合物 脯氨酸 组氨酸 甘氨酸 

分 类 号：O614.121[理学—无机化学]