四(对-硝基)苯基卟啉合钴、锰、铁、锌配合物电化学和光谱电化学性质的研究  

STUDING ON THE ELECTROCHEMICAL AND SPECTROELECTROCHEMICAL CHARACTERISTICS OF MESO TETRAKIS(4NITROPHENY)PORPHYRINATO COBALT, MANGANESE,IRON,ZINC COMPLEX

作　　者：陶建中[1] 王三虎 娄天军[1] 姚树文 孙浩然[2] 师同顺[2] 

机构地区：[1]河南职业技术师范学院化工系 [2]吉林大学化学系

出　　处：《化学研究与应用》1999年第3期268-271,共4页Chemical Research and Application

摘　　要：应用循环伏安法、现场紫外可见光谱电化学方法及现场ＦＴ—ＩＲ光谱电化学方法研究了标题配合物不同氧化态的电位及光谱特征，指认了各步电极反应发生的点位，研究了硝基对不同氧化态金属卟啉电学性质。The electrochamical and spectroelectrochemical characteristis of the title complex were studied by cyclic voltammetry,insitu UVvisible and FT-IR spectroelectrochemistry.The positiones of the electrode reaction were confirmed.The effects of the Nitrogroup on the electrochemical and spectroelectrochemical characteristics of the different oxidation state metalloporphyrins were studied.

关 键 词：卟啉 钴 锰 铁 锌 配合物 苯基 金属卟啉 硝基 

分 类 号：O614.81[理学—无机化学] O614.241[理学—化学]