三甲基镓与氮杂冠醚配合物的合成与表征(Ⅰ)  

SYNTHESIS AND CHARACTERIZATION OF COMPLEXES FORMED\= BY TRIMETHYL GALLIUM AND AZACROWN ETHERS

作　　者：田敬智[1] 张进琪[1] 杨民民 沈曦[1] 邹惠仙[1] 

机构地区：[1]南京大学化学化工学院

出　　处：《无机化学学报》1999年第4期462-466,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家863高技术研究项目

摘　　要：合成了八个新型的三甲基镓与侧链含酚羟基的氮杂冠醚所生成的配合物，用元素分析、红外、核磁共振和质谱的方法进行了表征，推断了它们的结构。\; Eight new complexes were prepared by the reaction of trimethyl gallium with azacrown ethers which contain the phenoxyl group. Their molecular structure were confirmed by elemental analysis, \+1H NMR, IR and MS. It is important to study the structure of the complexes for seeking new MO source and studying MOCVD techniques.\=\;

关 键 词：三甲基镓 氮杂冠醚 合成 配合物 

分 类 号：O627.32[理学—有机化学]