Synthesis,Crystal Structure and Electrochemical Property of the Ferrocenyl Schiff-base (E)-N’(Ferrocene Ethylidene)Picolino Hydrazide  

作　　者：李传碧 孙丽娟 张首才 张爱萍 富超 王家军 

机构地区：[1]Chemistry College of Jilin Normal University [2]Key Laboratory of Preparation and Applications of Environmental Friendly Materials,Jilin Normal University

出　　处：《Chinese Journal of Structural Chemistry》2011年第3期308-311,共4页结构化学（英文）

基　　金：supported by the Chemistry College of Jilin Normal University

摘　　要：A novel Schiff-base compound based on ferrocene C18H17OFeN3 （1） has been synthesized and characterized by X-ray diffraction. The title compound crystallizes in monoclinic, space group P21/c with a = 19.2343（17）, b = 10.5084（9）, c = 7.9373（7） A, β = 97.7740°, Z = 4, V = 1589.6（2） A^3, Dc = 1.451 g/cm^3, μ（MoKα） = 0.956 mm^-1, F（000） = 720, the final R = 0.0343 and wR = 0.0973 for 2759 observed reflections （I 〉 2σ（I））. Electrochemical measurements exhibit that compound 1 undergoes a reversible one-electron redox process.A novel Schiff-base compound based on ferrocene C18H17OFeN3 （1） has been synthesized and characterized by X-ray diffraction. The title compound crystallizes in monoclinic, space group P21/c with a = 19.2343（17）, b = 10.5084（9）, c = 7.9373（7） A, β = 97.7740°, Z = 4, V = 1589.6（2） A^3, Dc = 1.451 g/cm^3, μ（MoKα） = 0.956 mm^-1, F（000） = 720, the final R = 0.0343 and wR = 0.0973 for 2759 observed reflections （I 〉 2σ（I））. Electrochemical measurements exhibit that compound 1 undergoes a reversible one-electron redox process.

关 键 词：crystal structure electrochemical property SCHIFF-BASE ACETYLFERROCENE 

分 类 号：O621.3[理学—有机化学]