环氧稀释剂(1,2,8,9-双环氧-4-乙烯基环己烯)合成方法研究进展  

The Research Development of the Synthesis Methods to Epoxide Diluent(1,2,8,9-diepoxide-4-vinylcyclohexene)

作　　者：孙浩伟[1] 陈浩然[2] 迟波[2] 李晓丹[2] 郭淑齐[2] 

机构地区：[1]海军驻哈尔滨地区舰船配套军事代表室,哈尔滨150046 [2]哈尔滨玻璃钢研究院,哈尔滨150036

出　　处：《纤维复合材料》2010年第4期41-42,40,共3页Fiber Composites

摘　　要：本文介绍了用有机过氧酸、次卤酸及其衍生物和过硫酸盐三种氧化剂合成4-乙烯基环己烯双环氧化合物的方法,并对几种方法进行了机理分析和比较,结果表明:采用过硫酸盐氧化法得到的收率最高(78%),而且方法简便,成本低廉。The synthesis methods,using three oxidizing agents of organic peroxide acid,hypochlorous acid and its derivatives,potassium hydrogen persulfate,of 4-vinylcyclohexene dioxide are introduced in details in this article.The reaction mechanism is also analyzed.Compared with these methods,the result shows that Potassium hydrogen persulfate is the most effective oxidizing agent,with which the 4-vinylcyclohexene dioxide is obtained conveniently and cheaply,the yield is 78%,the highest one of all.

关 键 词：4-乙烯基环己烯双环氧化合物 环氧活性稀释剂 脂环族环氧树脂 

分 类 号：TQ231.2[化学工程—有机化工]