Iron-catalyzed bromination of aryl azides by N-bromosuccinimide:Efficient method for the synthesis of brominated aryl azides  

作　　者：Hui Jin Zhen Dong Huang Chun Xiang Kuang Xiao Kun Wang 

机构地区：[1]Department of Chemistry, Tongji University, Siping Road 1239, Shanghai 200092, China [2]Zhejiang Citrus Research Institute, Taizhou 318020, China

出　　处：《Chinese Chemical Letters》2011年第3期310-313,共4页中国化学快报（英文版）

基　　金：supported by National Natural Science Foundation of China(No30873153);the Key Projects of Shanghai in Biomedical(No08431902700);the Scientific Research Foundation of State Education Ministry for the Returned Overseas Chinese Scholars

摘　　要：An efficient and mild protocol for bromination of aryl azides with N-bromosuccinimide（NBS） under FeCl_3 catalysis in 1,2- dichloroethane was developed.It is proved to be an efficient method for obtaining brominated aryl azides.An efficient and mild protocol for bromination of aryl azides with N-bromosuccinimide（NBS） under FeCl_3 catalysis in 1,2- dichloroethane was developed.It is proved to be an efficient method for obtaining brominated aryl azides.

关 键 词：Iron-catalyzed Aryl azides N-BROMOSUCCINIMIDE BROMINATION 

分 类 号：TQ421.12[化学工程] V512[航空宇航科学与技术—航空宇航推进理论与工程]