溶剂浮选-高效液相色谱法测定水体中氯苯类环境激素的方法研究  

Study on Determination of Chlorobenzene Environmental Hormone in Water Samples by Solvent Sublation-High Performance Liquid Chromatograhy

作　　者：史春丽[1] 高楼军[1] 柴红梅[1] 

机构地区：[1]延安大学化学与化工学院,陕西延安716000

出　　处：《江西师范大学学报（自然科学版）》2011年第1期24-27,共4页Journal of Jiangxi Normal University(Natural Science Edition)

基　　金：陕西省教育厅专项科研计划(09JK814);延安市科技计划(2008KS-15)资助项目

摘　　要：采用溶剂浮选法分离富集水体中的痕量对氯苯酚、对二氯苯、三氯苯和六氯苯,分别对浮选溶剂、试液pH值、氮气流速、浮选时间等因素对浮选效果的影响进行优化,优选出最佳浮选条件,用高效液相色谱法测定各组分含量.采用所述方法对5个不同采样点的水样进行测定,方法加标回收率为82.9%-98.6%,RSD为0.82%-3.42%.A novel method for separating and enriching 4-chlorophenol,paradichlorobenzene,1,2,4-trichlorobenzene and hexachlorbenzene in the water samples by solvent sublation and determing them by high performance liquid chromatography has been developed.The effects of sublation solvent,pH of the solution,nitrogen flow rate and sublation time ect.The proposed method was used to determine five samples of water,the recoveries of the spiked sample were from 82.9% to 98.6%,and RSD values were from 0.82% to 3.42%.

关 键 词：溶剂浮选 高效液相色谱 对氯苯酚 对二氯苯 三氯苯 六氯苯 

分 类 号：O657.7[理学—分析化学]