Studies of the Oxidation of Hexabenzylhexaazaisowurtzitane  

作　　者：李亚裕 王琳 林秋汉 马巧丽 庞思平 于永忠 

机构地区：[1]School of Materials Science and Engineering,Beijing Institute of Technology [2]Beijing Institute of Aerospace Testing Technology [3]China Ordnange Industrial Standardization Research Institute

出　　处：《Journal of Beijing Institute of Technology》2010年第4期476-479,共4页北京理工大学学报（英文版）

基　　金：Sponsored by the National Natural Science Foundation of China(20772011)

摘　　要：A series of oxidation reactions of hexabenzylhexaazaisowurtzitane（HBIW,1） were studied.Compound 1 was treated with potassium permanganate in CH2Cl2 by adding Na2CO3 to adjust pH to 7-8 to obtain tetrabenzoyldibenzylhexaazaisowurtzitane（3） with a yield of 70%.With acetic anhydride（Ac2O） as solvent,monoacetyltribenzoyldibenzylhexaazaisowurtzitane（4）,diacetyldibenzoyldibenzylhexaazaisowurtzitane（5）,triacetylmonobenzoyldibenzylhexaazaisowurtzitane（6） and tetraacetyldibenzylhexaazaisowurtzitane（7） were also obtained from the oxidation of compound 1.The results show that only the oxidative cleavage of the cage system in compound 1 was observed in most cases.The cleavage was a cation catalysis mechanism.A series of oxidation reactions of hexabenzylhexaazaisowurtzitane（HBIW,1） were studied.Compound 1 was treated with potassium permanganate in CH2Cl2 by adding Na2CO3 to adjust pH to 7-8 to obtain tetrabenzoyldibenzylhexaazaisowurtzitane（3） with a yield of 70%.With acetic anhydride（Ac2O） as solvent,monoacetyltribenzoyldibenzylhexaazaisowurtzitane（4）,diacetyldibenzoyldibenzylhexaazaisowurtzitane（5）,triacetylmonobenzoyldibenzylhexaazaisowurtzitane（6） and tetraacetyldibenzylhexaazaisowurtzitane（7） were also obtained from the oxidation of compound 1.The results show that only the oxidative cleavage of the cage system in compound 1 was observed in most cases.The cleavage was a cation catalysis mechanism.

关 键 词：HEXABENZYLHEXAAZAISOWURTZITANE oxidation cleavage cage system CATION 

分 类 号：O626.2[理学—有机化学]