一系列功能性四苯基卟啉衍生物的合成及表征  

Synthesis and characterization of a series of functionalized tetraphenylporphyrin derivatives

作　　者：宋斌[1] 王亮[1] 杨家祥[1] 

机构地区：[1]安徽大学化学化工学院,安徽合肥230039

出　　处：《安徽大学学报（自然科学版）》2011年第2期89-93,共5页Journal of Anhui University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(50873001)

摘　　要：以苯甲醛和吡咯为原料通过Adler缩合的方法合成了四苯基卟啉(TPP),以此为母体,采用Vilsmeier甲酰化反应合成了2-甲酰基-5,10,15,20-四苯基卟啉(FTPP),以此为中间体,通过Wittig反应合成了一系列四苯基卟啉衍生物.用傅里叶变换红外光谱、核磁共振氢谱、碳谱及MALDI-TOF质谱等手段对目标产物的结构进行了表征.并且初步研究了化合物L3的光学性质,其主要发射峰在650 nm,是纯正的红光材料.Tetraphenylporphyrin（TPP）,as a precursor,was synthesized from benzaldehyde and pyrrole by Adler condensation.2-Formyl-5,10,15,20-tetraphenyl-porphyrin（FTPP） was obtained by Vilsmeier reaction from TPP.A series of tetraphenylporphyrin derivatives were synthesized via Wittig reaction based on FTPP.Their structures were characterized by FT-IR,1HNMR,13CNMR and MALDI-TOF mass spectra.And the linear optical properties of L3 were also studied.Its major emmision peak was at 650 nm,which showed it was pure red material.

关 键 词：四苯基卟啉 合成 表征 光学性质 

分 类 号：O625.6[理学—有机化学]