苯胺氧化羰基化反应条件研究  

The Study of Reactive Conditions of Oxidative Carbonylation of Aniline

作　　者：王文峰[1] 张藩贤[2] 许翩翩[2] 

机构地区：[1]福州大学化学系,福建福州350002 [2]厦门大学化学系,福建厦门361005

出　　处：《福州大学学报（自然科学版）》1999年第5期80-83,共4页Journal of Fuzhou University(Natural Science Edition)

摘　　要：苯胺氧化羰基化采用Ｐｄ／Ｃ 为催化剂， 产物为苯氨基甲酸乙酯， 是均相催化反应多相化的典型例子－ 通过对温度、反应时间、氧分压等的仔细摸索， 找到了反应的最佳条件，The oxidative carbonylation of aniline with Pd/C as catalyst can produce ethy1 N-phenyl carbamate, which is a typical example of homogeneous catalytic reaction We have found the optimum reactive condition after studying on temperature、reactive time、oxygen partial pressure et al We have analysed the byproducts and have affirmed their source

关 键 词：苯胺 羰基化 苯氨基甲酸乙酯 氧化 EPC 

分 类 号：O625.523[理学—有机化学]