一种新型含二茂铁基三角架配体的合成与表征  

Synthesis and Characterization of a New Tripodal Ligand Containing Ferrocenyl Group

作　　者：肖文[1] 卢忠林[1] 邓良容[1] 苏成勇[1] 康北笙[1] 

机构地区：[1]中山大学化学与化学工程学院,广州510275

出　　处：《中山大学学报（自然科学版）》1999年第5期127-128,共2页Acta Scientiarum Naturalium Universitatis Sunyatseni

基　　金：国家自然科学基金;上海有机所金属有机开放室基金

摘　　要：A new tripodal ligand containing ferrocenyl and hydrazone groups was synthesized by the condensation of ferrocenylcarbonylhydrazine with tris {[2 (2 formylphenyl)oxo]ethyl}amine and characterized by elemental analyses, IR and 1H NMR. It is expected to be an important ligand to react with transition metals to give functional coordination complexes with interesting physical chemical properties. Studies on its reactions and properties are in progress.A new tripodal ligand containing ferrocenyl and hydrazone groups was synthesized by the condensation of ferrocenylcarbonylhydrazine with tris {[2 (2 formylphenyl)oxo]ethyl}amine and characterized by elemental analyses, IR and 1H NMR. It is expected to be an important ligand to react with transition metals to give functional coordination complexes with interesting physical chemical properties. Studies on its reactions and properties are in progress.

关 键 词：三角架配体 二茂铁基 缩合反应 合成 表征 

分 类 号：O627.81[理学—有机化学] O641.4[理学—化学]