取代基酞菁铜的合成与表征  

Synthesis and Characterization for Substituents Copper(Ⅱ)Phthalocyanine

作　　者：夏道成[1,2] 姚纪欢[1] 韩双[1] 马会宣[1] 刘慧景[1] 

机构地区：[1]运城学院化学系,山西运城044000 [2]东北师范大学化学学院,吉林长春130012

出　　处：《山西大同大学学报（自然科学版）》2011年第2期30-33,共4页Journal of Shanxi Datong University(Natural Science Edition)

基　　金：国家自然科学基金资助项目[61006034];山西省青年基金资助项目[2010021010-3];运城学院院级重点项目[975175];东北师范大学校内博士后项目[111900026]

摘　　要：首先以3,6-二羟基邻苯二甲腈和氯代正丁烷为起始反应物,在无水碳酸钾的催化作用下,经亲核取代反应,在DMF(N,N-二甲基甲酰胺)溶剂中合成了中间配体3,6-二丁氧基邻苯二腈,再以此配体和氯化亚铜为前体,采用DBU液相催化法合成了周边烷氧基取代的1,4,8,11,15,18,22,25-八丁氧基酞菁铜,经过元素分析、红外、荧光、紫外可见光谱和原子吸收表征证明,产物就是目标化合物取代基酞菁铜。In this article,we first take 3,6-dihydroxy-phthalonitrile and chlorinated n-butane as the starting reactants to prepare 1,4,8,11,15,18,22,25-octa-butoxy copper phthalocyanine,3,6-dibutoxy phthalonitrile were prepared through nucleophilic substitution reaction in the solvent of DMF under the catalysis of anhydrous potassium carbonate.The mixture of 3,6-dibutoxy phthalonitrile and CuCl were used as precursors to synthesis 1,4,8,11,15,18,22,25-octa-butoxy copper phthalocyanine which was generated by cyclotetramerisation in the presence of 1,8-diazabicyclo undec-7-ene（DBU）.At last,the compound was characterized by elemental analysis,infrared,fluorescence and UV-visible spectrum and atomic absorption,which were proving its structure.Thus confirmed that the product was the target compound.

关 键 词：邻苯二甲腈 酞菁 合成 红外光谱 表征 

分 类 号：O613.2[理学—无机化学]