Predissociation of the b^3Пg （v=9） State of He2 Excimer  

He2分子b^3Пg（v=9）态的预解离

作　　者：李传亮[1] 邓伦毕[1] 张俊丽[1] 杨晓华[1,2] 陈扬骎[1] 

机构地区：[1]华东师范大学精密光谱科学与技术国家重点实验室,物理系,上海200062 [2]南通大学理学院,南通226007

出　　处：《Chinese Journal of Chemical Physics》2011年第2期125-128,I0003,共5页化学物理学报（英文）

基　　金：Acknowledgments： This work is supported by the National Natural Science Foundation of China （No.11034002 and No.11004062）, the National Key Basic Research and Development Program of China （No.2010CB922903 and No.2011CB21602）, and the Basic Key Program of Shanghai Municipality （No.07JC14017）. Chuan-liang Li is grateful to the support of the PhD Program Scholarship Fund of the East China Normal University 2009. The authors thank Pro- fessor Robert J. LeRoy from University of Waterloo for providing his BCONT, RKR and LEVEL programs,and authors are also particularly grateful to Dr. Xing- can Dai from JI-LA and NIST for his helpful and useful suggestions and discussions in simulation.

摘　　要：The predissociation of the v=9 level in the b^3Пg state by the 3∑u^＋ state of helium eximer （He2） was studied based on the newly observed （9, 3） band in the b^3Пg （v=9） system in the region of 12065-12445 cm^-1 employing optical heterodyne-concentration modulation absorption spectroscopy. With the help of the previous potential energy curves and molecular constants of He2, the corresponding predissociation mechanism for the b^3Пg （v=9） state was analyzed. An RKR potential energy curve of b^3Пg and an ab initio potential curve of 3∑g^＋ were used to calculate the predissociation linewidths that show basic agreement with observations, which can quantitatively explain the experiments.

关 键 词：Helium eximer PREDISSOCIATION Concentration modulation absorption spectroscopy 

分 类 号：O[理学]