若干地区出土部分商周青铜器的矿料来源研究  

Provenance of the Material for Bronze Vessels of the Shang and Zhou Dynasties unearthed from Some Areas of China

作　　者：魏国锋[1] 秦颍[2] 王昌燧[3] 刘博 杨立新[5] 徐天进[6] 张国茂 龚长根[8] 谢尧亭[9] 

机构地区：[1]浙江大学文物与博物馆学系,化学系,杭州310027 [2]中国科学技术大学科技史与科技考古系,合肥230026 [3]中国科学院研究生院科技史与科技考古系,北京100049 [4]辽宁省博物馆,沈阳110003 [5]安徽省文物考古研究所,合肥230000 [6]北京大学文博学院,北京100871 [7]安徽省铜陵市博物馆,安徽铜陵244000 [8]黄石市博物馆,湖北黄石435002 [9]山西省考古研究所,太原030000

出　　处：《地质学报》2011年第3期445-458,共14页Acta Geologica Sinica

基　　金：中国科学院知识创新工程项目(编号KJCX3.SYW.N12);“985工程”二期建设资助项目(编号985-2-201);陕西师范大学中央高校基本科研业务费专项资金(编号GK200902013)资助的成果

摘　　要：本工作采用ICP-AES方法,测试分析了若干地区出土青铜器残片的微量元素,初步探索了它们的矿料来源。将青铜器与铜绿山、铜陵、南陵、中条山、照壁山等先秦矿冶遗址铜锭或铜块的特征微量元素进行比较研究后,发现安徽境内青铜器的铜矿料主要来自长江中下游的古铜矿,而辽西地区和侯马青铜器的铜料则可能来自大井铜矿或其周边铜矿。同时,研究指出,Au、Ag、As、Sb、Bi、Se、Te、Co、Ni以及Mo、Zn等特征微量元素组合,对识别青铜器矿料来源具有指示意义,它表明,采用微量元素示踪法,探索青铜器的矿料来源是切实可行的,尤为适用于不同铜成矿带的示踪。This paper probes into the provenance of material for the bronze vessels in Shang and Zhou Dynasties from some areas in China using Inductively Coupled Plasma Atomic Emission Spectrometer（ICP-AES）to analyze trace elements.The trace elements from bronze vessels were compared with those from ingot and copper pieces from Pre-Qin Dynastiy＇s mining and smelting sites such as Tonglüshan,Tongling,Nanling,Zhongtiaoshan and Zhaobishan.Our results reveal that the copper of the bronze vessels in Anhui Province came from ancient copper ores of the Middle and Lower reaches of Yangtze River and the copper of bronze vessels found in Western Liaoning Province and Houma came from the Dajing copper ores.Meanwhile,this research indicates trace elements Au,Ag,As,Sb,Bi,Se,Te,Co,Ni,Mo and Zn,etc.in copper ores are indicative of the provenance of material of the bronze vessels.It is feasible to determine the possible provenance of the bronze vessels on the basis of analysis of trace element in bronze vessels.

关 键 词：青铜器 矿料来源 微量元素 电感藕合等离子发射光谱 

分 类 号：P618.41[天文地球—矿床学]