循环伏安法测定溶液中Fe^(3+)和Fe^(2+)浓度比  

Study on the concentration of Fe^(3+) to Fe^(2+) in solution by cyclic voltammetry

作　　者：李云[1] 王晨雪[1] 尚游[2] 尚世智[1] 郭建伟[1] 

机构地区：[1]沈阳化工大学应用化学学院,辽宁沈阳110142 [2]沈阳市公安局刑事警察支队技术处,辽宁沈阳110002

出　　处：《冶金分析》2011年第3期72-75,共4页Metallurgical Analysis

基　　金：国家自然科学基金(50705092);辽宁省教育厅项目(2008s184)

摘　　要：采用循环伏安法(CV)测定铁泥制备Fe3O4过程中Fe3+与Fe2+浓度比值的变化,为该工艺过程提供方便、快捷的监测方法。在实验条件下,溶液中的Fe3+与Fe2+组成可逆的氧化还原体系,产生一对峰形良好的氧化还原峰。对影响峰电流的扫描速度、pH值及干扰离子等因素进行考察,结果表明,扫描速度在0.002~0.01 V/s、pH在1.5~2.5时对氧化峰电流及还原峰电流没有影响;溶液中存在的SO42-离子在实验范围内对体系基本无干扰。Fe3+的浓度在0.000 8~0.008 4 mol/L呈线性关系,相关系数为0.999 9,相对标准偏差(n=7)在0.70%~2.0%之间。该法与标准重铬酸钾滴定法对比,相对误差为1.7%。The concentration change of Fe3＋ to Fe2＋ in the preparation process of Fe3O4 from iron mud was determined by cyclic voltammetry（CV）,which provided a simple and rapid monitoring method for this technological process.Under the experimental conditions,the Fe3＋ and Fe2＋ in solution formed reversible redox system,generating a pair of redox peak in good shape.The factors influencing the peak current were investigated,including the scanning rate,pH and interference ions.The results showed that the scanning rate in the range of 0.002-0.01 V/s and pH in the range of 1.5-2.5 had no influence on the oxidation peak current and reduction peak current.SO42-in the solution basically had no interference with the system under experimental conditions.The relationship was linear for Fe3＋ in the range of 0.000 8-0.008 4 mol/L with correlation coefficient of 0.999 9.The relative standard deviation（RSD,n=7） was 0.70 %-2.0 %.The proposed method was compared with standard potassium dichromate titrimetry with a relative error of 1.7 %.

关 键 词：循环伏安法 Fe3+和Fe2+浓度比 重铬酸钾滴定法 

分 类 号：TQ138.11[化学工程—无机化工]