高温高压条件下甲烷和二氧化碳溶解度试验  

Experiment on solubility of CH_4 and CO_2 at high temperature and high pressure

作　　者：范泓澈[1] 黄志龙[1] 袁剑[2] 高岗[1] 童传新 冯冲[1] 

机构地区：[1]中国石油大学地球科学学院,北京102249 [2]中国石化西南油气分公司川西采气厂,四川德阳618000 [3]中海石油有限公司湛江分公司,广东湛江523057

出　　处：《中国石油大学学报（自然科学版）》2011年第2期6-11,19,共7页Journal of China University of Petroleum(Edition of Natural Science)

基　　金：国家'973'重点基础研究发展计划项目(2007CB209503);中国海洋石油有限公司综合科研项目(Z2008SLZJ-FN0149)

摘　　要：根据不同温度和压力条件下测得的甲烷和二氧化碳两种气体在碳酸氢钠型水中的溶解度数据,对两种气体的溶解度与温度、压力及地层水矿化度之间的关系进行研究。结果表明：在地层水中的溶解机制不同,导致两种气体的溶解度值随温度、压力条件的变化具有不同的演变特征;综合前人低温（小于90℃）测试的溶解度数据,可将甲烷溶解度与温度之间的演变关系划分为缓慢递减（0~80℃）、快速递增（80~150℃）和缓慢递增（大于150℃）3个阶段;二氧化碳溶解度随温度的升高而逐渐降低,随压力升高而逐渐增大,其溶解与析离能力受压力影响更为明显;实际地层中,两种气体间溶解度的差异演变影响了天然气的空间分布。The relationships between the solubility of the two gases and temperature,pressure as well as the salinity of formation water were studied based on the solubility data of methane gas（CH4） and carbon dioxide gas（CO2） in sodium bicarbonate type water at different temperature and pressure.The results show that the different dissolution mechanism in the formation water results in solubility values of two gases with the different evolution characteristics as temperature and pressure changing.Connecting with the predecessors experimental results under low-temperature condition（less than 90 ℃）,the relationships of the solubility of methane gas and temperature were divided into three stages of slowly descending phase（0-80 ℃）,rapidly increasing phase（80-150 ℃） and slowly increasing phase（greater than 150 ℃）.The solubility of carbon dioxide gas dissolving in formation water gradually decreases with temperature increasing and gradually increases with pressure increasing,so it is obvious that the pressure controls the dissolution and exsolution of carbon dioxide gas in formation water.The differential evolution characteristics of the solubility between two kinds of gases affect the spatial distribution of natural gas.

关 键 词：高温高压 甲烷 二氧化碳 溶解度 析离能力 

分 类 号：TE133.1[石油与天然气工程—油气勘探]