含二甲基二烯丙基氯化铵阳离子单元聚合物的合成研究进展  

Research Progress in the Synthesis of Cationic Polymers Containing Dimethyldiallylammonium Chloride

作　　者：刘程[1] 张跃军[1] 

机构地区：[1]南京理工大学化工学院,江苏南京210094

出　　处：《精细化工》2011年第5期417-423,432,共8页Fine Chemicals

基　　金："十五"国家科技攻关项目(2003BA327C)~~

摘　　要：介绍了含二甲基二烯丙基氯化铵(DMDAAC)阳离子单元的聚合物及合成方法的研究进展。首先,从二甲基二烯丙基氯化铵的单体分子结构出发,分析了其物理化学性质;进而,以单体分子所含双键可参与的闭环加成聚合反应为主线,分别归纳了其作为聚合反应中间体可参加的均聚反应和共聚反应,较为详细地介绍了以DMDAAC为结构单元的二元、多元结构聚丙烯酰胺、与特殊功能单体的共聚物和以其为基改性的天然产物及合成方法,指出了已有研究工作的特色与不足。最后,针对含DMDAAC单元聚合物的研究工作现状,提出可通过分子结构设计、改性来合成新型含DMDAAC单元聚合物以满足多个领域中的应用需要,加强该类聚合物的应用研究也是推动该类聚合物合成研究工作快速发展的重要动力。The research progress of cationic polymers containing dimethyldiallylammonium chloride（DMDAAC） as chain members was reviewed in this paper.With the double bonds which were able to participate in addition polymerization as the main line,the homo-and co-polymerizations of DMDAAC were summarized based on its molecular structure and physical chemical properties.The synthesis of DMDAAC-based polyacrylamide,copolymer with specific functional groups and modified natural products were discussed in detail.And the features of the research work completed were also pointed out.Finally,it had been suggested that new polymers containing DMDAAC should be synthesized by molecular structure design and modification to meet the needs of their application in different fields.However,the further application researches of these polymers would be also important in promoting the development of such polymers.

关 键 词：二甲基二烯丙基氯化铵 阳离子聚合物 单体聚合 

分 类 号：TQ316.3[化学工程—高聚物工业] O631.5[理学—高分子化学]