正丁胺对晶态层状苯乙烯基膦酸-磷酸氢锆的插层研究  

Intercalation of n-Butylamine into Layered Crystalline Zirconium Phenylvinylphosphonate-Phosphate

作　　者：张怀志[1] 傅相锴[1] 王长炜[1] 罗云飞[1] 贾紫永 

机构地区：[1]西南大学化学化工学院,重庆市应用化学市级重点实验室,三峡库区生态环境教育部重点实验室,重庆400715

出　　处：《无机化学学报》2011年第5期872-876,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家科技部科技中小型企业技术创新基金(No.09C26215112399);国家人力资源和社会保障部留学人员回国创业启动支持计划(人社厅发2009(143号))资助项目

摘　　要：合成了晶态层状有机-无机多功能材料苯乙烯基膦酸-磷酸氢锆(α-ZPPVPA),并研究了正丁胺(BA)对α-ZPPVPA的插层性能。用元素分析、XRD、IR、TG、SEM和TEM等分析方法对α-ZPPVPA及其插层化合物α-ZPPVPA-BA进行了结构表征和形貌分析。结果表明,正丁胺成功地插入了α-ZPPVPA层板之间,层间距为2.41 nm,正丁胺的插入使α-ZPPVPA的层间距(1.66 nm)增大了0.75 nm,插入的正丁胺在α-ZPPVPA中呈双分子层排列,且苯乙烯基侧链不饱和双键的存在不影响α-ZPPVPA与正丁胺的插层反应。Layered crystalline zirconium phenylvinylphosphonate-phosphate（α-ZPPVPA） was synthesized as organic-inorganic multifunctional material.The intercalation complex of n-butylamine（BA） into α-ZPPVPA was studied.α-ZPPVPA and its intercalation complex α-ZPPVPA-BA were characterized by elemental analysis,XRD,IR,TG,SEM and TEM.The results indicated that n-butylamines were successfully intercalated into α-ZPPVPA interlayer and the interlayer distance of α-ZPPVPA-BA was 0.75 nm larger than that of α-ZPPVPA（1.66 nm）.The n-butylamines,which intercalated into α-ZPPVPA,formed bi-molecule layer.The existence of unsaturated double bonds has no influence on the intercalation reaction of n-butylamine into α-ZPPVPA

关 键 词：苯乙烯基膦酸-磷酸氢锆 层状化合物 插层 正丁胺 

分 类 号：O614.41[理学—无机化学] O613.62[理学—化学]