四组分一锅法合成三苯胺-吡啶衍生物  

Four-component one-pot synthesis of triphenylamine-pyridine derivatives

作　　者：张欣[1] 刘霞[1] 冯国良[1] 张红利[1] 耿丽君[1] 

机构地区：[1]河北科技大学理学院,河北石家庄050018

出　　处：《河北工业科技》2011年第3期142-145,152,共5页Hebei Journal of Industrial Science and Technology

摘　　要：以三苯胺醛、苯乙酮、3-氰基乙酰基吲哚和醋酸铵为原料,分别在传统加热回流和微波辐射条件下,利用四组分一锅法反应,简便地合成了一系列的三苯胺-吡啶衍生物。该方法具有产率较高、操作简单等优点。产物的结构通过了1H NMR,IR和E.A.表征。A series of triphenylamine-pyridine derivatives were synthesized by four-component one-pot reaction of triphenylamine aldehyde, aeetophenone, 3-eyanoacetyl indole and ammonium acetate at refluxing temperature and microwave irradiation. This method has the advantages of good yield and easy operation. The structures of the products were characterized by 1 H NMR spectra, IR and elemental analysis.

关 键 词：多组分反应 吡啶衍生物 三苯胺醛 3-氰基乙酰基吲哚 微波辐射 

分 类 号：O621.3[理学—有机化学]