聚碳酸亚丙酯多元醇聚氨酯的绿色合成  

The Green Synthesis Process of Polyurethane with Poly Propylene Polyols

作　　者：张学舟[1] 田恒水[1] 潘冬冬[1] 

机构地区：[1]华东理工大学化学工程系,上海200237

出　　处：《广东化工》2011年第5期151-152,共2页Guangdong Chemical Industry

摘　　要：文章以酯交换缩聚法合成聚氨酯树脂,绿色环保,避开了光气路线及有毒的异氰酸酯的使用。选择的原料都是由二氧化碳路线合成,具有减少二氧化碳排放的重大意义。选择1,6-六亚甲基二氨基甲酸甲酯及聚碳酸亚丙酯多元醇为原料,在反应摩尔比为1∶1,使用B型催化剂,催化剂用量为0.12 wt%,反应温度133℃反应6 h的情况下,可以得到质均分子量为5717的聚氨酯。In the paper,transesterification polycondensation synthesis process of polyurethane was studied to avoid the toxic phosgene routes and the use of isocyanates.1,6-hexamethylene dicarbamate（HDC） and Poly propylene polyols（PPC） were selected as raw material.HDC and PPC were all synthesized from carbon dioxide,so this route had a positive effect to reduce carbon emissions.Choose B as catalyst,the dosage was 0.12 wt%,molar ratio of HDC to PPC was 1∶1,with 133 ℃ and react for 6 h.Finally get the polyurethane with Mw=5717.

关 键 词：聚氨酯 酯交换缩聚 非光气 

分 类 号：TQ[化学工程]