Heavy metal distribution patterns and environmental quality assessment of the mariculture areas in Nanao,Shantou  

汕头南澳海水养殖区不同水层重金属的分布和环境质量评价(英文)

作　　者：周艳晖[1] 白燕[1] 李联盛[1] 杨宇峰[2] 

机构地区：[1]暨南大学化学系,广东广州510632 [2]水生生物研究所水体富营养化与赤潮防治广东省教育厅重点实验室,广东广州510632

出　　处：《Marine Science Bulletin》2011年第1期71-79,共9页海洋通报（英文版）

基　　金：supported by the National Natural Science Foundation of China (No.40673062)

摘　　要：The Fe, Zn, Mn and Pb concentrations in the seawater dissolved phase were investigated in the sea-surface microlayer （SML）, subsurface water （SSW） and bottom water （BW） samples collected at of three mariculture areas of the Nanao Island ocean zone. The results showed that the SML and the BW were important compartments for these heavy metals in the mariculture areas and the concentrations varied from 23.0 μg/L to 268.0 μg/L（Fe）, 11.0 μg/L to 82.2 μg/L（Zn）, 1.5 μg/L to 11.0 μg/L（Mn） and 6.0 μg/L to 40.5 μg/L（Pb） in SSW, while a clear enrichment is observed in the SML, where these ranged from 27.5 μg/L to 286.5 μg/L（Fe）, 13.5/lg/L to 89.0μg/L（Zn）, 3.0μg/L to 12.0 μg/L（Mn） and 7.0 μg/L to 46.0μg/L（Pb）. The enrichment factors were in the range of 1.07 - 1.39 which showed a slight enrichment. The average enrichment factors of Fe, Zn, Pb and Mn were 1.18, 1.13, 1.12 and 1.30, respectively. The average enrichment factors in shellfish, fish and gracilaria lemaneaformis farming areas were 1.26, 1.19 and 1.11, respectively, which showed that the surface activity was highest in the shellfish farming area. Furthermore, the heavy metals concentrations were lowest in the gracUaria lemaneaformis farming area. The results of single factor contamination index showed that the investigated areas were slightly contaminated with Zn, while the partial farming areas were seriously contaminated with Pd during a certain period of time.利用电感耦合等离子发射光谱(ICP-AES)方法测定了汕头南澳海水养殖区溶解态的重金属在不同水层中的分布。在龙须菜、鱼类和贝类养殖水域检出Fe、Zn、Mn、Pb等重金属,其中微表层(SML)和底层(BW)是这些重金属的主要存在区域。这些重金属在微表层(SML)中的浓度(Fe27.5-286.5μg/L,Zn13.5-89.0μg/L,Mn3.0-12.0μg/L,Pb7.0-46.0μg/L)明显高于其在亚表层(SSW)中的浓度(Fe23.0-268.0μg/L,Zn11.0-82.2μg/L,Mn1.5-11.0μg/L,Pb6.0-40.5μg/L),表明微表层发生富集现象,富集系数(EF)在1.07-1.39范围内属于轻微富集,其中Mn的平均富集系数最高(EF=1.30),其他金属相近。平均富集系数以贝类养殖水域最高(1.26),其次为鱼类养殖水域(1.19),龙须菜养殖水域最低(1.11),表明贝类养殖水域表面活性最大。龙须菜养殖水域重金属含量较其他养殖水域低。单因子污染评价显示,南澳养殖海域已经受到Zn低度污染,部分水域在一定时间内Pb的污染严重。

关 键 词：sea-surface microlayer enrichment factors heavy metal single factorcontamination index 

分 类 号：X820.2[环境科学与工程—环境工程]