咪唑桥异多核配合物的合成和表征  

SYNTHESIS AND CHARACTERIZATIONOF IMIDAZOLATE BRIDGED HETEROPOLYNUCLEAR COMPLEXES

作　　者：刘之俊[1] 陈东[1] 唐雯霞[1] 

机构地区：[1]南京大学配位化学研究所,南京,210008

出　　处：《无机化学学报》1990年第2期198-203,共6页Chinese Journal of Inorganic Chemistry

摘　　要：本文报道了六种含ida,edma及dien的Cu-Im-Co,Cu-Im-Pt,Co-Im-Cu-Im-Co和Co-Im-Zn-Im-Co异双核,异三核配合物的合成与表征。用~1H NMR及反射光谱证实配合物中咪唑桥的存在,并对配合物中Cu的空间构型及成键性质进行了讨论。Six new heteropolynuclear complexes containing tridentate ligand , ida and edma, were synthesized and characterized. The imidazolate bridges in the title complexes were ascertained by NMR and reflectance spectroscopies.The configuration and bonding character of the complexes are discussed.

关 键 词：铜 锌 咪唑桥 异多核配合物 

分 类 号：O614.121[理学—无机化学]