Recent developments in homobimetallic reagents and catalysts for organic synthesis  

作　　者：WU Wei GU DeLiang WANG ShiMeng NING YingNan MAO GuoLiang 

机构地区：[1]Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China

出　　处：《Chinese Science Bulletin》2011年第17期1753-1769,共17页

基　　金：supported by the National Natural Science Foundation of China (20972025);the China National Petroleum Corporation (CNPC) Innovation Foundation (2010D-5006-0504)

摘　　要：Organometallics are a family of useful organic chemicals because they play important roles in organic synthesis as reagents and as catalysts.They can be classified according to the number of metals they contain.Bimetallic compounds are important organometallics and they are either homobimetallic or heterobimetallic depending on whether the two metals are the same or different.In this paper,we focus on homobimetallic compounds.Homobimetallic compounds are generally used as dianions to react with electrophiles in organic synthesis.Recently,homobimetallics have also been used as catalysts in organic reactions such as in asymmetric reactions.Organometallics are a family of useful organic chemicals because they play important roles in organic synthesis as reagents and as catalysts. They can be classified according to the number of metals they contain. Bimetallic compounds are important organometallics and they are either homobimetallic or heterobimetallic depending on whether the two metals are the same or different. In this paper, we focus on homobimetallic compounds. Homobimetallic compounds are generally used as dianions to react with electrophiles in organic synthesis. Recently, homobimetallics have also been used as catalysts in organic reactions such as in asymmetric reactions.

关 键 词：有机合成试剂 催化剂 有机金属化合物 有机化工原料 双金属化合物 有机反应 不对称反应 数量分类 

分 类 号：O643.36[理学—物理化学] TQ421[理学—化学]