炭黑填充导电硅橡胶的结构与性能  

Structure and Properties of Electric Conducting Silicon Rubber Filled With Carbon Black

作　　者：张继华[1] 任灵[1] 王立峰[1] 赵云峰[1] 

机构地区：[1]航天材料及工艺研究所,北京100076

出　　处：《宇航材料工艺》2011年第2期79-82,86,共5页Aerospace Materials & Technology

摘　　要：采用SEM、TGA等表征了炭黑填充导电硅橡胶的性能及结构,并研究其导电机理。结果表明,乙炔炭黑含量对导电硅橡胶的力学性能有明显影响。含量超过45 phr后,其体积电阻率变化不明显,炭黑在橡胶内部形成"球簇"和"簇链"结构,因而炭黑的增多,增加了"导电通路",降低橡胶的体积电阻率;导电硅橡胶的最佳耐热性填充量为50 phr,此时随温度的增加,其拉伸强度下降;在100℃下长期老化后的导电性能下降。Electric conducting silicon rubber was prepared by filling acetylene carbon black into the rubber.The structures of the conducting rubbers were characterized by SEM and TGA.Then their conducting mechanism was investigated in detail.The results show that the content of carbon black obviously affects mechanical properties of the conducting silicon rubber.But the change of volume resistivity is not obvious when the carbon black content is beyond 45 phr.The structure of ＂grain/cluster＂ and ＂chain/cluster＂ formed in the conducting rubber.Therefore,the ＂electric channels and tunnels＂ increased and the volume resistivity decreased.The content of 50 phr is the optimal quantity of thermal-resistance for the silicon rubber.With the increase of temperature,the tensile strength of conducting rubbers with 50 phr carbon black decreased gradually.After aging at the temperature of 100℃,the conducting property of silicon rubber reduced.

关 键 词：硅橡胶 乙炔炭黑 导电 性能 

分 类 号：TQ333.93[化学工程—橡胶工业]