环己烯分子氧氧化多相催化剂研究进展  

Research progress of heterogeneous catalysts for cyclohexene oxidation with molecular oxygen

作　　者：蔡贞玉[1] 王磊[1] 朱明乔[1] 

机构地区：[1]浙江大学化学工程与生物工程学系,浙江杭州310027

出　　处：《合成纤维工业》2011年第3期43-46,共4页China Synthetic Fiber Industry

基　　金：浙江省自然科学基金(Y4080247);浙江省自然科学基金杰出青年团队(R4090358);浙江省重大科技计划项目(2010C01035)

摘　　要：根据催化剂主组分的不同,综述了国内外环己烯分子氧氧化多相催化剂的研究进展;主要介绍了钴系、锰系、铁系及镍系催化剂在环己烯分子氧氧化中的应用及其优缺点。指出负载型纳米金催化剂与传统的钴、锰催化剂相结合制备双活性中心催化剂在环己烯分子氧氧化中有较好的应用前景。The research progress of heterogeneous catalysts for cyclohexene oxidation with molecular oxygen was reviewed based on the dominating components of catalysts in China and abroad. The application of cobalt, manganese, iron and nickel catalysts in cyclohexene oxidation with molecular oxygen was emphatically introduced, as were their advantages and disadvantages. It was pointed out that dual-active center catalysts prepared from the combination of supported nano-gold catalyst and traditional cobalt or manganese catalyst would have fairly good application prospects in cyclohexene oxidation with molecular oxygen.

关 键 词：环己烯 分子氧 多相催化剂 氧化 进展 

分 类 号：O643.32[理学—物理化学]