PET缩聚催化剂乙二醇盐的合成与应用技术进展  

Progress in synthesis and application technology of ethylene glycol alkoxides catalysts for PET polycondensation

作　　者：沈国良[1] 宁桂玲[1] 董优嘉[2] 刘红宇[2] 李银苹[2] 

机构地区：[1]大连理工大学化工学院,辽宁大连116012 [2]沈阳工业大学石油化工学院,辽宁辽阳111003

出　　处：《合成纤维工业》2011年第3期47-50,54,共5页China Synthetic Fiber Industry

基　　金：辽宁省教育厅科技计划项目(2005303);辽宁省自然科学基金资助项目(20102169)

摘　　要：介绍了聚对苯二甲酸乙二醇酯(PET)缩聚反应用催化剂乙二醇盐的合成与应用进展;详述了乙二醇锑、乙二醇钛、乙二醇铝催化剂的合成和应用,以及应用各种催化剂的优缺点;指出乙二醇锑催化剂活性高,但污染严重,乙二醇铝催化剂毒性低,催化活性也低。综合考虑,绿色环保的乙二醇钛及其复合催化剂将是聚酯的良好催化剂,将替代现有锑系催化剂,前景看好。The progress in the synthesis and application of ethylene glycol alkoxides catalyst for polyethylene terephthalate （PET） pnlycondensation was reviewed. The synthesis and application of ethylene glycol antimony, ethylene glycol titanium and ethylene glycol aluminum catalysts were introduced and discussed in details, as were their advantages and disadvantages. It was pointed out that ethylene glycol antimony catalyst had high activity with serious pollution when ethylene glycol aluminum catalyst had low toxicity and activity;green environmental-friendly titanium and its composite catalysts should be favorable catalysts for polyester polycondensation which would have wide application prospects as a substitute for antimony catalyst system for polyester polycondensation.

关 键 词：聚对苯二甲酸乙二醇酯 催化剂 乙二醇盐 金属醇盐 合成 应用 

分 类 号：TQ323.41[化学工程—合成树脂塑料工业]